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本文选用抗坏血酸(ASA)/过氧化氢(H2O2)引发体系,采用乳液聚合工艺,低温引发有机硅-丙烯酸酯共聚.系统考察了聚合反应温度,氧化剂......
以丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)、八甲基环四硅氧烷(D4)为单体,乙烯基三甲氧基硅烷(Z-6300)为偶联剂,采用半连续乳液聚合......
Three difunctional low polarity acrylate monomers were synthesized in this study.After purification, the obtained acryla......
The bulk polymerization of acrylate was carried out with 2-ethyl hexyl acrylate and acrylic acid as copolymers and 819 a......
Chlorinated polypropylene(CPP)has a good adhesion on polyolefin plastic,it is often used as the adhesion promoter in the......
采用溶液聚合法将含有乙烯基的硅树脂共聚到丙烯酸酯链节中,合成了硅树脂改性丙烯酸酯压敏胶,并研究了硅树脂的最佳加入时间和加入......
A modified total synthesis of cystothiazole A is described. In this synthetic strategy, a one-step transformation of acy......
The reaction of ethyl α-bromocinnamates with tetrabutyl ammonium fluoride(TBAF) was influenced largely by the position ......
第二个顺序率常数, k 2 被决定了让三双分子的一天一夜桤木的反应证明离子的液体的高粘性能是在执行一天一夜桤木的反应的一个有害......
DIFFERENT TYPES OF MICROFIBRILLATED CELLULOSE AS FILLER MATERIALS IN POLYSODIUM ACRYLATE SUPERABSORB
Three types of microfibrillated cellulose(MFC)with differences in structure and surface charge were used at low concentr......
Photoinitiating Characteristics of Benzophenone Derivatives as Type II Macromolecular Photoinitiator
Dodecyl-benzophenone(DBP) and hexadecoxyl-benzophenone(HDBP) as type II photoinitiators used for radical photopolymeriza......
P(AA-MA)copolymers composed of acrylic acid and methyl acrylate with different molecular weights and sequence structures......
Determination of Crosslinking and Grafting in Polyurethane-acrylic Hybrid Material and Their Theoret
A theoretical method to calculate the mode of polyurethane(PU) prepolymers grafted to polyacrylic(PAC) was presented. Us......
THERMAL AND MECHANICAL PROPERTIES OF POLYLACTIDE TOUGHENED WITH A BUTYL ACRYLATE-ETHYL ACRYLATE-GLYC
In this work, a specific polylactide(PLA) 4032D was melt-mixed with a new toughener: butyl acrylate(BA), ethyl acrylate(......
In this report,zinc acrylate copolymers were synthesized by used different organic acid as the side chain structure.Thes......
In this report,zinc acrylate copolymers were synthesized by used different organic acid as the side chain structure.Thes......
SYNTHESIS AND CHARACTERIZATION OF AN ACRYLATE POLYMER CONTAINING CHLORINE-1,3-DIOXALANE GROUPS IN SI
Poly[2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methyl acrylate,poly(CPhDMA),was synthesized with radical polymerization proce......
A novel magnetic weak acid resin NDMC-1 was prepared in the presence of methyl acrylate(MA),divinylbenzene(DVB) and tita......
Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments
Copolymers with super segregated structure of hydrophilic methoxy poly(ethylene glycol)(mPEG) and fluorophilic poly(1H,1......
Effects of baria on propane oxidation activity of Pd/Al_2O_3 catalyst:Pd–BaO interaction and reactio
The BaO-modified Pd/Al2O3exhibits much better catalytic activity than Pd/Al2O3for C3H8 oxidation both before and after t......
FUNCTIONALIZING PS MICROSPHERES BY SUPERCRITICAL DEPOSITION OF P(S-b-tBA) FOR DIVERSE INTERFACIAL PR
Polystyrene(PS) microspheres were functionalized with poly(styrene-b-tert-butyl acrylate)(P(S-b-tBA)) by adsorption from......
INFLUENCE OF ZnSt_2 ON STRUCTURE OF ACRYLATE-BASED IONOMERS WITH DIFFERENT LANTHANIDE(La(Ⅲ)) ION AND
A series of acrylate processing aid(ACR)-based ionomers with different lanthanide(La(Ⅲ)) ion and acid contents were syn......
Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and o......
A novel poly(vinyl chloride)-supported Pd complex was found to be a highly active catalyst for the Heck and Sonogashira ......
A simple and efficient procedure for the preparation of silica-bonded N-propylpiperazine sodium n-propionate(SBPPSP) by ......
Synthesis and properties of UV curable polyurethane acrylates based on two different hydroxyethyl ac
Two kinds of UV curable polyurethane acrylate oligomers(PUPA and PUCA) were synthesized via the addition reaction betwee......
Copolymers of methyl methacrylate(MMA) and acrylate terminated poly(ethylene oxide-co-ethylene carbonate) (PEOC) macromo......
Stable high-solids-content acrylate emulsion were obtained with a nonionic polymerizable emulsifier allyloxy nonylphenox......
Thermo-sensitive Poly(DEGMMA-co-MEA) Microgels: Synthesis, Characterization and Interfacial Interact
The novel microgels, poly[di(ethylene glycol) methyl ether methacrylate-co-2-methoxyethyl acrylate] poly(DEGMMA-co-MEA) ......
DABCO-based ionic liquids:Green and efficient catalysts with a dual catalytic role for aza-Michael a
Four recoverable and reusable ionic liquids based on 1,4-diazobicyclo[2.2.2]octane(DABCO) have been synthesized to catal......
PEG Assisted Hydrothermal Synthesis of β-Na YF_4:Yb~(3+),Er~(3+) Microrods for Upconversion Photolum
β-Na YF4:Yb3+,Er3+ microrods with average length of 10 μm and diameter of 2.5 μm were synthesized through hydrotherma......
In this review, a recent development of cationic ?-diimine palladium(II) complexes for ethylene polymerization and copol......
Synthesis of multifunctional ABC stars with a reduction-labile arm by consecutive ROP, RAFT and ATRP
This study aims at versatile synthesis of 3-arm ABC-type(A=poly(?-caprolactone), PCL; B=poly(N-isopropylacrylamide), PNI......
Atom transfer radical polymerization of methyl acrylate,methyl methacrylate and styrene in the prese
Transition metal-mediated atom transfer radical polymerization(ATRP) is a ‘‘living’’/controlled radical polymerizati......
In this work,we report the hybrid copolymerization of various cyclic monomers and vinyl monomers.Our studies demonstrate......
Probing the pH-dependent chain dynamics of poly(acrylate acid) in concentrated solution by using a c
We report a novel strategy to study the chain dynamics of poly(acrylic acid)(PAA)in a relative concentrated solution(1.0......
ACYCLIC DIENE METATHESIS POLYMERIZATION OF TAILOR-MADE MONOMERS TOWARDS SEQUENCE-REGULATED VINYL COP
Acyclic diene metathesis polymerization (ADMET) enables convenient transfer of sequential information of the designed mo......
Preparation of Core-Shell Structured Polyacrylic Modifiers and Effects of the Core-Shell Weight Rati
Core-shell structured polyacrylic(named CSSP) impact modifiers consisting of a rubbery poly(n-butyl acrylate) core and a......
A manganese-catalyzed bicyclic annulation of imines with α,β-unsaturated esters via C–H activation is described, whic......
Effect of fluorine groups and different terminal chains on the electro-isomerization of azobenzene l
A series of azobenzene liquid crystals with one or two terminal acrylate groups were synthesized and their polymers were......
Homopolymer(PBIP) containing 2,6-bis(1’-methylbenzimidazolyl)pyridine(Me BIP) ligands in the side chain was synthesized......
Probing the effects of external species on poly(acrylate acid) chain dynamics by using cationic AIE-
We report here our results on the investigation of the chain dynamics of poly(acrylic acid) in aqueous solution. The con......
The synthesis of amphiphilic aggregation-induced emission(AIE) dyes based organic nanoparticles has recently attracted i......
A macromer, methoxypolyethylene glycol acrylate(MPEGAA), was synthesized by direct esterification using methoxypolyethyl......
DABCO-catalyzed multi-component domino reactions for green and efficient synthesis of novel 3-oxo-3H
An efficient,convenient and environmentally benign procedure for the synthesis of novel 3-oxo-3Hbenzo[a]pyrano[2.3-c]phe......
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Synthesis and bulk polymerization kinetics of monomer dehydroabietic acid-(2-acryloyloxy-ethoxy)-eth
A bulk polymerization monomer dehydroabietic acid-(2-acryloyloxy-ethoxy)-ethyl ester(DHADG-AC) was synthesized from dehy......
A Pd(Ⅱ)-catalyzed ortho-olefination of aromatic acetic esters is described which features with an excellent funcitional......
In order to improve the stabilization and spinnability of polyacrylonitrile,a bifunctional comonomer containing both est......